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hydrolysis of nitriles
When nitriles are hydrolysed you can think of them reacting with water in two stages - first to produce an amide, and then the ammonium salt of a carboxylic acid.
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Hydrolysis of Nitriles
Nitriles can be hydrolyzed on both acidic and basic conditions. Acidic conditions typically yield carboxylic acids, while the basic conditions can give you either carboxylic acids or amides.
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As expected, when nitriles are hydrolyzed (by nucleophilic addition of water followed by nucleophile elimination), they form either carboxylic acids or amides, depending on the conditions.
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The Hydrolysis of Nitriles
This page looks at the hydrolysis of nitriles under either acidic or alkaline conditions to make carboxylic acids or their salts.
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The Mechanism of Nitrile Hydrolysis To Carboxylic Acid
In both cases, the transformation consists of two main parts: conversion of the nitrile to an amide and hydrolysis of the amide to the corresponding carboxylic acid.
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